Fuel production

Solar chemical processes use solar energy to drive chemical reactions. These processes offset energy that would otherwise come from a fossil fuel source and can also convert solar energy into storable and transportable fuels. Solar induced chemical reactions can be divided into thermochemical or photochemical. A variety of fuels can be produced by artificial photosynthesis. The multielectron catalytic chemistry involved in making carbon-based fuels (such as methanol) from reduction of carbon dioxide is challenging; a feasible alternative is hydrogen production from protons, though use of water as the source of electrons (as plants do) requires mastering the multielectron oxidation of two water molecules to molecular oxygen. Some have envisaged working solar fuel plants in coastal metropolitan areas by 2050- the splitting of sea water providing hydrogen to be run through adjacent fuel-cell electric power plants and the pure water by-product going directly into the municipal water system. Another vision involves all human structures covering the earth's surface (i.e., roads, vehicles and buildings) doing photosynthesis more efficiently than plants.

Hydrogen production technologies been a significant area of solar chemical research since the 1970s. Aside from electrolysis driven by photovoltaic or photochemical cells, several thermochemical processes have also been explored. One such route uses concentrators to split water into oxygen and hydrogen at high temperatures (2300-2600 °C). Another approach uses the heat from solar concentrators to drive the steam reformation of natural gas thereby increasing the overall hydrogen yield compared to conventional reforming methods. Thermochemical cycles characterized by the decomposition and regeneration of reactants present another avenue for hydrogen production. The Solzinc process under development at the Weizmann Institute uses a 1 MW solar furnace to decompose zinc oxide (ZnO) at temperatures above 1200 °C. This initial reaction produces pure zinc, which can subsequently be reacted with water to produce hydrogen.